In shops, price is a fair guide to level. If it costs more than 5 times the price of newbie gear, it's either high-level or overpriced. Once you're Veteran, this ceases to be a problem except at very special shops - ones you won't find in starting cities.
If you took an item from a monster who's "tough challenge" or better, there's a moderate chance of losing it with each log in.
So logging out just for a quick bathroom run probably isn't the best of ideas, at least at low level. If you're not in a dangerous area, sleeping for 5 RL minutes isn't a problem. Just keep in mind that danger includes PCs of opposite ideals, as well as monsters.
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